Poly[{μ3-3-[4-(1H-imidazol-1-ylmethyl)phenyl]prop-2-enoato-κN:η2:κO}copper(I)]
نویسنده
چکیده
In the coordination polymer, [Cu(I)(C(13)H(11)N(2)O(2))](n), the Cu(I) atom exists in a trigonal-planar geometry that is defined by the C=C unit, the imidazole N atom and carboxyl-ate O atoms from three different ozagrel ligands, resulting in the formation of a three-dimensional framework.
منابع مشابه
Poly[diaquabis{μ-5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolato}copper(II)]
In the title compound, [Cu(C(11)H(9)N(6))(2)(H(2)O)(2)](n), the Cu(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phen-yl]tetra-zolate ligands and two water mol-ecules in a distorted octa-hedral geometry. The ligands bridge the Cu(II) atoms, leading to the formation of a two-dimensional network parallel to (100). The structure is f...
متن کاملCrystal structure of catena-poly[[bis(acetato-κO)copper(II)]-bis[μ-4-(1H-imidazol-1-yl)phenol]-κ2 N 3:O;κ2 O:N 3]
In the title compound, [Cu(CH3COO)2(C9H8N2O)2] n , the CuII ion resides on a centre of inversion, displaying a tetra-gonally distorted octa-hedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl)phenol ligands is associated w...
متن کاملCrystal structure of catena-poly[[diaquacobalt(II)]-bis[μ-5-(4-carboxyylatophenyl)picolinato]-κ3 N,O 2:O 5;κ3 O 5:N,O 2-[diaquacobalt(II)]-μ-1-[4-(1H-imidazol-1-yl)phenyl]-1H-imidazole-κ2 N 3:N 3′]
The asymmetric unit of the title polymeric Co(II) complex, [Co2(C13H7NO4)2(C12H10N4)(H2O)4] n , contains a Co(II) cation, a 5-(4-carboxyl-atophen-yl)picolinate dianion, two coordination water mol-ecules and half of 1-[4-(1H-imidazol-1-yl)phen-yl]-1H-imidazole ligand. The Co(II) cation is coordinated by two picolinate dianions, two water mol-ecules and one 1-[4-(1H-imidazol-1-yl)phen-yl]-1H-imid...
متن کاملBis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN 3]bis(nitrato-κO)copper(II)
A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa-hedron distorted by Jahn-Teller effects. Inter-molecular O-H⋯O, O-H⋯N, N-H⋯O and N-H⋯N hydrogen-bonding inter-actions...
متن کاملcatena-Poly[(trans-diaquacadmium)-bis{μ-5-[4-(1H-imidazol-1-yl)phenyl]tetrazol-1-ido}]
In the title compound, [Cd(C(10)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) atom lies on an inversion centre and is coordinated by four N atoms from 5-[4-(1H-imidazol-1-yl)phen-yl]tetra-zol-1-ide ligands and two O atoms from the coordinated water mol-ecules in an octa-hedral arrangement. The complex polymeric chains are inter-connected via inter-molecular water O-H⋯N hydrogen bonds into a three-dimensi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011